Valory Music Co.Thomas Rhett is teaming up with pop/rock act Fall Out Boy for a collaboration on the 49th Annual CMA Awards next month. They join previously-announced show openers Hank Williams, Jr. and Eric Church, who will be performing the Waylon Jennings classic, “Are You Ready for the Country.”

Carrie Underwood and Brad Paisley host the 49th Annual CMA Awards, coming up Wednesday, November 4 at 8 p.m. ET on ABC.

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