Capitol NashvilleKeith Urban performed an intimate concert Tuesday at Nashville leather goods shop Peter Nappi to celebrate the launch of Rolling Stone Country, the new website devoted to the country format. He kicked off the hits-filled set with a cover of Dr. Hook and the Medicine Show‘s “Cover of the Rolling Stone.”

The capacity crowd featured industry heavyweights mingling with country stars, including Brett Eldredge, Hunter Hayes, Eli Young Band, Chris Young, Martina McBride, Kellie Pickler, Wynonna, Ashley Monroe, Angaleena Presley, Leah Turner, Brothers Osborne, Sunny Sweeney and Kristian Bush.

Sam Palladio,  Jonathan Jackson and Chaley Rose of ABC’s Nashville were also spotted in the crowd along with former Vice President Al Gore and model Karen Elson.

Rolling Stone releases an all-country issue this week celebrating the launch of Rolling Stone Country. Eric Church and Miranda Lambert are featured on the issues’ two collectible covers.

Copyright 2014 ABC News Radio